Sedimentation Velocity Analytical Ultracentrifugation

نویسنده

  • Stephen E. Harding
چکیده

(b) Sedimentation equilibrium: an experiment performed at a lower speed so that the sedimentation and backdiffirsion forces are of comparable magnitudes and therefore give rise to an equilibrium distribution of solute concentration. Because there is no net transport at equilibrium, shape effects do not come into play and the distribution becomes an absolute function of molecular mass for a single solute. For an interacting system the distribution is an absolute reflection of the mass action relationship between the species participating in the chemical equilibrium reaction (concentrations as well as molecular masses of the participating species).

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تاریخ انتشار 2011